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標題: Titlebook: Electronic Transitions and the High Pressure Chemistry and Physics of Solids; H. G. Drickamer,C. W. Frank Book 1973 H. G. Drickamer and C. [打印本頁]

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作者: 雀斑    時間: 2025-3-21 23:26

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Phenomenological Description of Continuous Electronic Transitions,hand, some electronic transitions, including those in compounds of iron involving changes in spin state or oxidation state, occur continuously over a range of pressure. In fact, for the reduction of ferric to ferrous iron, one can frequently represent the conversion over a considerable range of pres
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Spin Changes in Iron Complexes,the interelectronic repulsion. It was also shown there that a ligand field of octahedral symmetry partially removes the degeneracy, giving a lower lying triplet of .(t.) symmetry and a higher energy doublet of .(e.) symmetry. We showed in Chapter 6 that for high spin complexes the ligand field incre
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作者: Exposition    時間: 2025-3-23 17:14
ons in the above volumes, Modern Very High Pressure Techniques, edited by Wentorf, High Pressure Methods in Solid State Research, by C. C. Bradley, The Accurate Characterization of the High Pressure Environment, edited by E. C. Lloyd, and a chapter in Volume 11 of Solid State Physics are devoted entirely to t978-94-011-6898-4978-94-011-6896-0
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作者: ascetic    時間: 2025-3-23 23:48
Electronic Transitions and the High Pressure Chemistry and Physics of Solids978-94-011-6896-0
作者: 圖表證明    時間: 2025-3-24 05:31
Electrophysiology of Chemoreception state consists of the ferrous ion and a collectively oxidized set of ligands. The presence of a ‘hole’ on the ligands decreases the probability that the Fe(II) site will exhibit typically ferrous behavior as regards metal-ligand vibrational frequency, etc. Much of the earlier data must be regarded
作者: disrupt    時間: 2025-3-24 06:36

作者: 高歌    時間: 2025-3-24 11:53
Thermal Versus Optical Transitions,We shall find that in many cases the thermal energy is apparently much smaller than the energy observed optically. We shall show that this is reasonable, and present an approximate relationship between them.
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作者: 過時    時間: 2025-3-24 19:00
https://doi.org/10.1007/978-3-662-55198-1or . electron systems. Finally, Pople and Beveridge [4] consider more recent approximate molecular orbital theories which may be applied to all valence electrons of a general three-dimensional molecule.
作者: 攀登    時間: 2025-3-25 01:30
Robert W. Matthews,Janice R. Matthewsmplexes or between ligand and metal in transition metal complexes; and finally, excitations from the valence band to the conduction band in insulators and semiconductors. In the following chapters we discuss orbital energy shifts which lead specifically to new ground states in a variety of systems.
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https://doi.org/10.1007/978-1-4020-8782-0pters 6, 8, 9, and 10 we saw that for a variety of systems this thermal occupation was highly probable at high pressure, and that these electronic transitions led to new spin states and oxidation states for iron, particularly when complexed to aromatic or quasi-aromatic molecules.
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de the two-volume Physics and Chemistry of High Pressure, edited by R. S. Bradley, and the series, Advances in High Pressure Research, as well as the report on the Lake George Conference in 1960. Solid state physics is well represented by Solids Under Pressure, edited by Paul and Warschauer, by Phys
作者: Mucosa    時間: 2025-3-26 11:35
Gillian Kidman,Niranjan Casinaderorbidden energy between bands. For an insulator or semiconductor there is a decrease in resistivity which may ultimately lead to metallic behavior. This is the classical picture observed in books like that of Seitz [1].
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作者: 單挑    時間: 2025-3-26 17:16
Insect Biochemistry and Function. Both of these factors increase the probability of a high spin to low spin conversion. (The increase in field is probably the major effect.) Since Griffith [1] has shown that an intermediate spin configuration is never the most stable in octahedral symmetry, we need only deal with high and low spin states at this point.
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Exploring the Medical Making of Patients,course, gives a measure of this difference, subject to definite restrictions. On the other hand, the process of electron transfer to establish a new ground state at high pressure is a thermal one. As we shall find it useful to relate these processes, it is important to understand their differences.
作者: 駕駛    時間: 2025-3-28 11:10
Labelling and Languaging the Other,hand, some electronic transitions, including those in compounds of iron involving changes in spin state or oxidation state, occur continuously over a range of pressure. In fact, for the reduction of ferric to ferrous iron, one can frequently represent the conversion over a considerable range of pres
作者: Robust    時間: 2025-3-28 15:48
Programmed Cell Death and Aging,lobars. We touch on the actual physical nature of the apparatus only to the degree necessary to give an idea as to the possibilities and limitations. The details necessary for construction of the apparatus appear in the literature [1–8]. We confine ourselves primarily to techniques used in this labo
作者: 大看臺    時間: 2025-3-28 21:59
Robert W. Matthews,Janice R. Matthewsne measures the shift by optical absorption although other techniques, such as M?ssbauer resonance, may give useful information. In this chapter we describe a variety of such shifts: relatively localized transitions such as those involving the d electrons of transition metals; excitations involving
作者: OUTRE    時間: 2025-3-29 01:56
Insect Biochemistry and Functionthe interelectronic repulsion. It was also shown there that a ligand field of octahedral symmetry partially removes the degeneracy, giving a lower lying triplet of .(t.) symmetry and a higher energy doublet of .(e.) symmetry. We showed in Chapter 6 that for high spin complexes the ligand field incre
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作者: 柱廊    時間: 2025-3-29 07:43
https://doi.org/10.1007/978-3-030-22780-7 now discuss two types of systems where both processes are occurring. We again use M?ssbauer resonance to identify the states present. The analyses of the M?ssbauer spectra are considerably more complex for these systems so that the quantitative aspects are less precise than for the system discussed
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作者: HIKE    時間: 2025-3-29 19:14
Synaptic Transmission in Insects,In this chapter we take up transitions which change the electrical properties of metals or compounds by establishing a new ground state for the system. Changes in physical rather than chemical properties are involved in these transitions, in contrast to the events discussed in later chapters.
作者: 土產(chǎn)    時間: 2025-3-29 22:26
Electronic Transitions in Metals and Insulator-Metal Transitions,In this chapter we take up transitions which change the electrical properties of metals or compounds by establishing a new ground state for the system. Changes in physical rather than chemical properties are involved in these transitions, in contrast to the events discussed in later chapters.
作者: Suggestions    時間: 2025-3-30 03:05
978-94-011-6898-4H. G. Drickamer and C. W. Frank 1973




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