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標(biāo)題: Titlebook: Electron Transfer Reactions in Organic Chemistry; Lennart Eberson Book 1987 Springer-Verlag Berlin Heidelberg 1987 catalysis.chemical reac [打印本頁]

作者: 令人不愉快    時(shí)間: 2025-3-21 19:37
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作者: scoliosis    時(shí)間: 2025-3-21 23:05
Concepts and Definitions,ncept in an unambiguous way. Clearly we must have a stringent definition of electron transfer before we can discuss it. Definitions are however never trivial and ambiguity is attached to the concept of electron transfer, depending on both time and user. It is therefore necessary of digress for a whi
作者: 同謀    時(shí)間: 2025-3-22 01:43
Theories of Electron Transfer in Organic Chemistry,ative relationships, and phenomenologically derived principles. If any unifying trends can be discerned over the period since organic chemistry was born around 1860, it is the tenacity by which the concept of the chemical bond has been retained from the early theory of structure, and the strong emph
作者: Lice692    時(shí)間: 2025-3-22 05:42
How to Use the Marcus Theory,itious level one can simply look at the factors which influence the two variables in the parabolic term of the Marcus equation, Δ.°′ and λ, and qualitatively assess their influence on the feasibility of an ET step. Δ.°′ is a thermodynamic quantity and is accessible for experimental determination, wh
作者: commodity    時(shí)間: 2025-3-22 11:34

作者: CERE    時(shí)間: 2025-3-22 16:42
Reactions Between Organic and Inorganic Non-metallic Species, not these processes are of a redox character, and hence fall within the scope of this book. This chapter will specifically deal with non-metallic inorganic redox reagents, among which we find most of the common electrophiles and nucleophiles, and discussed here because of their potential alternativ
作者: CERE    時(shí)間: 2025-3-22 17:06

作者: Arbitrary    時(shí)間: 2025-3-22 23:27
Electricity and Light Promoted ET,more detail. As pointed out in Chapter I, electrochemistry is the science of ET, as has been recognized for a long time, whereas the all-pervasive nature of photochemical ET has been generally appreciated only during the last 10–15 years. Also, the ET character of the converse process, emission of l
作者: 攤位    時(shí)間: 2025-3-23 01:33

作者: Anthem    時(shí)間: 2025-3-23 09:05

作者: 種子    時(shí)間: 2025-3-23 09:55
Applications of Outer-sphere Electron Transfer,ortance of ET in the chemical fixation of solar energy, where we want to improve upon Nature’s biological mechanisms in order to secure a long-lasting supply of energy. This represents a great challenge to the chemist, although it does not exactly reflect a humble mind! Of course, this task logicall
作者: 消耗    時(shí)間: 2025-3-23 16:00
Epilogue,c chemistry oriented than my 1982 review [1], In choosing this approach, I was strongly influenced by the propensity of organic chemists to describe quantitative data in terms of free energy relationships, of which the Marcus treatment constitutes a quadratic variety. The two variables that go into
作者: Goblet-Cells    時(shí)間: 2025-3-23 18:21
Reactivity and Structure: Concepts in Organic Chemistryhttp://image.papertrans.cn/e/image/306171.jpg
作者: 北極人    時(shí)間: 2025-3-23 23:53
Manage Your Mood to Follow Your Intuitionrved-arrow mechanisms, and with rare exceptions [2], notions of .-electron organic chemistry did not enjoy much acceptance in the past. Free radicals have certainly been part of the organic chemist’s mechanistic arsenal for a long time, but only recently have radical reactions been explored for synt
作者: 吸氣    時(shí)間: 2025-3-24 03:21

作者: 悄悄移動(dòng)    時(shí)間: 2025-3-24 09:37
Being Confident in your Thesis,ative relationships, and phenomenologically derived principles. If any unifying trends can be discerned over the period since organic chemistry was born around 1860, it is the tenacity by which the concept of the chemical bond has been retained from the early theory of structure, and the strong emph
作者: 后天習(xí)得    時(shí)間: 2025-3-24 12:32
Jessica Eise,Kenneth Alan Fosteritious level one can simply look at the factors which influence the two variables in the parabolic term of the Marcus equation, Δ.°′ and λ, and qualitatively assess their influence on the feasibility of an ET step. Δ.°′ is a thermodynamic quantity and is accessible for experimental determination, wh
作者: 粗糙    時(shí)間: 2025-3-24 15:31

作者: 惰性女人    時(shí)間: 2025-3-24 19:43

作者: 座右銘    時(shí)間: 2025-3-24 23:19
Win Procurements Before They Go Public,als and radical ions) and closed-shell species (even-electron molecules and ions). Also here this distinction is neither rigorous nor very fruitful, except possibly for purpose of classification; the occurrence of outer-sphere ET is again dependent on the relative redox reactivity of the species inv
作者: 令人心醉    時(shí)間: 2025-3-25 06:48
Reporting Internal and Externalmore detail. As pointed out in Chapter I, electrochemistry is the science of ET, as has been recognized for a long time, whereas the all-pervasive nature of photochemical ET has been generally appreciated only during the last 10–15 years. Also, the ET character of the converse process, emission of l
作者: ABOUT    時(shí)間: 2025-3-25 08:45

作者: 音樂學(xué)者    時(shí)間: 2025-3-25 13:42
https://doi.org/10.1007/978-1-4842-3691-8xists such a thing as an outer-sphere ET mechanism (remember that this depends on a definition of outer-sphere ET as occurring via a transition state with maximally 1 kcal mol. (4 kJmol.) of electronic interaction between the reactants) the problem can be given a distinct formulation: Are our elemen
作者: AFFIX    時(shí)間: 2025-3-25 17:19
Mathematics, the Common Base for Science,ortance of ET in the chemical fixation of solar energy, where we want to improve upon Nature’s biological mechanisms in order to secure a long-lasting supply of energy. This represents a great challenge to the chemist, although it does not exactly reflect a humble mind! Of course, this task logicall
作者: 槍支    時(shí)間: 2025-3-25 23:08
Lutgart Van den Berghe,Abigail Levrauc chemistry oriented than my 1982 review [1], In choosing this approach, I was strongly influenced by the propensity of organic chemists to describe quantitative data in terms of free energy relationships, of which the Marcus treatment constitutes a quadratic variety. The two variables that go into
作者: 搬運(yùn)工    時(shí)間: 2025-3-26 01:52
Constant Current Generators (CCG)Metal ions of interest in redox processes exist in several oxidation states of more or less pronounced stability.
作者: 使人煩燥    時(shí)間: 2025-3-26 04:53
Reaction Between Organic and Metal Ion Species,Metal ions of interest in redox processes exist in several oxidation states of more or less pronounced stability.
作者: 補(bǔ)角    時(shí)間: 2025-3-26 10:13
How to Examine the Nervous Systemncept in an unambiguous way. Clearly we must have a stringent definition of electron transfer before we can discuss it. Definitions are however never trivial and ambiguity is attached to the concept of electron transfer, depending on both time and user. It is therefore necessary of digress for a while on this problem, dull as it may seem.
作者: exceptional    時(shí)間: 2025-3-26 15:13
Gesell’s Solution to Achieve the SDGs mechanistic goal we can realistically aim for and, particularly, what kind of description we can expect to accomplish by experimental tests. Chapter II provides a suitable starting point for this discussion.
作者: Medicaid    時(shí)間: 2025-3-26 20:46
,What Is ‘Invention’ And Can It Be Taught?,ly through the pioneering efforts of Bunnett [5], Kornblum [6] and Russell [7]. The development of this reaction type has strongly contributed to the current activity in organic ET chemistry. In this Chapter, we shall mainly be concerned with the ET aspects of ETC processes.
作者: 憂傷    時(shí)間: 2025-3-26 22:47

作者: Perceive    時(shí)間: 2025-3-27 03:16

作者: chassis    時(shí)間: 2025-3-27 05:16

作者: CRAB    時(shí)間: 2025-3-27 12:23
978-3-642-72546-3Springer-Verlag Berlin Heidelberg 1987
作者: 精確    時(shí)間: 2025-3-27 17:36

作者: 不適當(dāng)    時(shí)間: 2025-3-27 21:30
https://doi.org/10.1007/978-3-642-72544-9catalysis; chemical reaction; electrochemistry; inorganic chemistry; metals; organic chemistry; oxygen; syn
作者: isotope    時(shí)間: 2025-3-27 22:07

作者: gregarious    時(shí)間: 2025-3-28 04:59
ET and Polar Mechanisms; How Are They Connected?,ite them in two steps, the initial one being of outer-sphere ET type? A clearcut case, to be discussed in more detail below (see Sect. XI.2.b) is the reaction between benzene and nitronium ion, the archetype of a polar, single transition state step (Fig. 1).
作者: 無脊椎    時(shí)間: 2025-3-28 09:36

作者: adequate-intake    時(shí)間: 2025-3-28 14:28

作者: 啤酒    時(shí)間: 2025-3-28 15:42

作者: overbearing    時(shí)間: 2025-3-28 20:47

作者: ESPY    時(shí)間: 2025-3-29 02:28

作者: Ganglion-Cyst    時(shí)間: 2025-3-29 05:34

作者: Modify    時(shí)間: 2025-3-29 11:17
Lutgart Van den Berghe,Abigail Levraus of standard potential and reorganization energy for organic redox couples, and I hope it has become clear that much work is needed before we have available table works of the same scope and quality as for inorganic redox couples.
作者: OCTO    時(shí)間: 2025-3-29 12:16
Epilogue,s of standard potential and reorganization energy for organic redox couples, and I hope it has become clear that much work is needed before we have available table works of the same scope and quality as for inorganic redox couples.
作者: mettlesome    時(shí)間: 2025-3-29 17:05

作者: falsehood    時(shí)間: 2025-3-29 21:50

作者: monologue    時(shí)間: 2025-3-30 01:39
Electron Transfer, a Neglected Concept in Organic Chemistry,have certainly been part of the organic chemist’s mechanistic arsenal for a long time, but only recently have radical reactions been explored for synthetic uses [3, 4] and only seldom has the chemistry of radical ions, products of one-electron transformations of neutral organic compounds, commanded attention outside a narrow circle of specialists.




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