標題: Titlebook: Catalysis by Unique Metal Ion Structures in Solid Matrices; From Science to Appl Gabriele Centi,Blanka Wichterlová,Alexis T. Bell Book 2001 [打印本頁] 作者: 文化修養(yǎng) 時間: 2025-3-21 19:58
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices影響因子(影響力)
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices影響因子(影響力)學科排名
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices網(wǎng)絡(luò)公開度
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices網(wǎng)絡(luò)公開度學科排名
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices被引頻次
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices被引頻次學科排名
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices年度引用
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices年度引用學科排名
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices讀者反饋
書目名稱Catalysis by Unique Metal Ion Structures in Solid Matrices讀者反饋學科排名
作者: 背信 時間: 2025-3-21 23:11
General Optimal Control Problemility is defined with reference to either reduction to metallic particles or demetallation to form metal oxide particles. The siting requirements and stability of binuclear cations, viz. [M-O-M]., are also examined.作者: single 時間: 2025-3-22 01:01 作者: 散開 時間: 2025-3-22 07:37
https://doi.org/10.1007/978-3-030-91059-4n numbers for Co/FER, MFI and MOR samples and thus enabled to characterize the average Co ion site in the zeolite framework. The results also indicated, in agreement with FTIR spectra, that Co ions deform the zeolite support to reach an optimal bonding with the framework.作者: Obedient 時間: 2025-3-22 12:47
The Limitless Horizons of Space Art,luminescence spectra are assigned to these types of sites. Cu. ions on the channel intersection (type I) bind NO stronger than naked Cu. ions and it is suggested that these sites are catalytically active. A possible explanation of the higher catalytic activity of Cu/ZSM-5 compared to Cu/FER is proposed.作者: 迫擊炮 時間: 2025-3-22 16:34
Sílvia Faria,José Lima,Paulo Costathe proton exchanges with metal cation. Ti-MCM- 41 was the most active among the metal ion-planted MCM-41 for catalytic asymmetric oxidation of sulphide with hydrogen peroxide in the presence of optically active tartaric acid in dichloromethane.作者: 迫擊炮 時間: 2025-3-22 20:01
Ion Exchange of Non-Framework Cations in Zeolites for Catalysis,l it, we can use it to our advantage in catalyzing a number of reactions. A survey of the impact of ion exchange upon several reactions is provided. Comparisons are made with regard to activity and cation siting within the zeolite. Finally, a listing of opportunities for future research is provided.作者: 過份艷麗 時間: 2025-3-23 00:52 作者: 叢林 時間: 2025-3-23 03:29
Mono- and Multinuclear Oxo-Cations in Zeolite Cavities,changed zeolite“. Binuclear oxo-ions, such as bipositive [Cu-O-Cu], [HO-Fe- O-Fe-OH], and [HO-Fe-O-O-Fe-OH] ions, in zeolite cavities are crucial in novel catalysts for NO. reduction and catalytic oscillation of N.O decomposition.作者: 推延 時間: 2025-3-23 08:00 作者: Ancestor 時間: 2025-3-23 12:27 作者: 外向者 時間: 2025-3-23 17:27
Asymmetric Oxidation of Sulphide on Metal Ion Planted in Mesoporous MCM-41,the proton exchanges with metal cation. Ti-MCM- 41 was the most active among the metal ion-planted MCM-41 for catalytic asymmetric oxidation of sulphide with hydrogen peroxide in the presence of optically active tartaric acid in dichloromethane.作者: negotiable 時間: 2025-3-23 21:53
Book 2001udingthe distribution of framework Al atoms in Si-rich zeolites,distribution and siting of charge-exchanged metal cations, electronic,adsorptive and catalytic properties of metal cations, and correlationof metal cation structure and siting with catalytic activity.作者: 危險 時間: 2025-3-23 23:12
1568-2609 ects, includingthe distribution of framework Al atoms in Si-rich zeolites,distribution and siting of charge-exchanged metal cations, electronic,adsorptive and catalytic properties of metal cations, and correlationof metal cation structure and siting with catalytic activity.978-0-7923-6875-5978-94-010-0782-5Series ISSN 1568-2609 作者: 粗鄙的人 時間: 2025-3-24 03:33
José Baptista,Filipe Lima,Adelaide Cerveirasignificant role in the photocatalytic decomposition of NO, i.e., an electron transfer from the s orbital of the excited state of Cu. or Ag. ions into the π. antibonding orbital of NO initiates the decomposition reaction of NO.作者: Alveolar-Bone 時間: 2025-3-24 10:14
Photocatalysis of Cations Incorporated within Zeolites,significant role in the photocatalytic decomposition of NO, i.e., an electron transfer from the s orbital of the excited state of Cu. or Ag. ions into the π. antibonding orbital of NO initiates the decomposition reaction of NO.作者: Influx 時間: 2025-3-24 13:36
Book 2001from the same cationic species containedin a bulk oxide or supported on amorphous carriers. This subject istreated to an extensive review, showing how an understanding of it isessential to the development of a new generation of solid catalysts.There are also exciting opportunities to shape the catal作者: 潛伏期 時間: 2025-3-24 16:16 作者: overshadow 時間: 2025-3-24 20:50
Electronic Structure of Transition-Metal Ion Containing Zeolites,dvanced to a level, still rapidly developing, where relatively large systems, including periodic systems, can be handled by all-electron calculations from the first principles. It is now possible to optimize geometries of zeolites with different cations and framework substituents and to predict their structural and electronic properties.作者: Congestion 時間: 2025-3-25 00:53 作者: 黑豹 時間: 2025-3-25 06:44 作者: 輕率看法 時間: 2025-3-25 08:58
M. V. Barkova,A. S. Strekalovskiydvanced to a level, still rapidly developing, where relatively large systems, including periodic systems, can be handled by all-electron calculations from the first principles. It is now possible to optimize geometries of zeolites with different cations and framework substituents and to predict their structural and electronic properties.作者: companion 時間: 2025-3-25 14:10
Laurence Mann,Jieun Kiaer,Emine ?ak?r) induce changes in the reactivity at the metal oxide due to the confinement of reactants/products in the zeolite cavities. These aspects are discussed with reference to Cu-, Fe-, V- and Mocontaining micro- and mesoporous materials in order to evidence prospects, but also limitations for the application of this new class of catalytic materials.作者: 最高峰 時間: 2025-3-25 17:15
1568-2609 roperties from the same cationic species containedin a bulk oxide or supported on amorphous carriers. This subject istreated to an extensive review, showing how an understanding of it isessential to the development of a new generation of solid catalysts.There are also exciting opportunities to shape作者: 瑣碎 時間: 2025-3-25 20:30 作者: Accolade 時間: 2025-3-26 00:51
Applications to Natural Resources,olitic ring with two Al ions, the sites with distantly placed aluminiums were also studied. It was shown that the latter tend to form oxygen bridged zinc cationic pairs. Such sites, as well as small zinc oxide clusters, exhibit a different enhanced reactivity towards alkanes compared to single zinc ions in cationic positions.作者: 協(xié)議 時間: 2025-3-26 06:52 作者: AMPLE 時間: 2025-3-26 10:25
Thomas Nordli,Noureddine Bouhmalamost active catalysts. The heterogeneous catalysts were more active than the corresponding homogeneous catalysts, which is concluded to be related to co-catalysis by the protons present in the zeolite.作者: 微枝末節(jié) 時間: 2025-3-26 12:56
https://doi.org/10.1007/978-3-030-91936-8erogeneous catalysts will be presented in some examples. The immobilisation will be demonstrated in the following two cases:.The catalysts obtained thereby are tested in different stereoselective reactions such as oxidation and hydrogenation.作者: MANIA 時間: 2025-3-26 18:36 作者: 土產(chǎn) 時間: 2025-3-27 00:02 作者: 文字 時間: 2025-3-27 04:41
Local Site Deformations in Zeolites by the Coordination of Cu(II),ed using multiconfigurational perturbation theory (CASPT2), and compared with experiment. It was shown that Cu(II) induces strong lattice deformations in the cation sites to achieve a four-fold planar coordination. The Cu(II) spectroscopic features are believed to be influenced by both the geometry and the Si/A1 distribution of the cation site.作者: Kidney-Failure 時間: 2025-3-27 09:14
Direct Addition of Amine N-H to CC Triple Bonds,most active catalysts. The heterogeneous catalysts were more active than the corresponding homogeneous catalysts, which is concluded to be related to co-catalysis by the protons present in the zeolite.作者: cogitate 時間: 2025-3-27 09:26 作者: 忙碌 時間: 2025-3-27 14:29
Towards a better understanding and terminology of the Oxide / Transition Metal Complex interactionstal ion ions (TMIs) with oxide matrices, with special emphasis on their relevance to the preparation of supported metal catalysts. As we will show, the current use of vocabulary is sometimes confused or misleading and would benefit from some systematisation. In particular, a sound reasoning on TMC/o作者: 價值在貶值 時間: 2025-3-27 18:43
Ion Exchange of Non-Framework Cations in Zeolites for Catalysis,ous approaches to ion exchange, including vapor transport techniques are also described. Some believe that incipient wetness of a zeolite is the same as ion exchange, don’t control pH, ignore the selection of the salt for exchange, or feel that the extent of exchange is independent of the Si/Al rati作者: Rinne-Test 時間: 2025-3-28 01:28
Single Metal Ions in Host Zeolite Matrices. Structure-Activity-Selectivity-Relationships, methane. To explain this effect of zeolite matrices, ligation of the Co ions in cationic sites of these zeolites as well as Co-ligand complexes with CO, NO, NH., NO. and H.O were described by using Vis spectra of Co ions and IR spectra in the region of skeletal and adsorbates vibrations, and EXAFS 作者: 玷污 時間: 2025-3-28 03:40
Siting and Stability of Metal Cations in Zeolites,ongst different cation-exchange sites depends on a variety of factors including, the charge on the cation, the Si/Al ratio of the zeolite, and the distribution of Al atoms in the zeolite framework. An overview is presented of recent theoretical efforts aimed at determining the distribution of charge作者: instill 時間: 2025-3-28 09:21
Mono- and Multinuclear Oxo-Cations in Zeolite Cavities,ved by dissipating their positive charge into three monopositive charges. Hydrolysis converts bare ions into oxo-ions that, unlike bare metal ions, can be reduced with CO. The number of “extra- lattice” oxygen (ELO) atoms can be derived from the amount of CO. formed in this process. The limiting num作者: 一瞥 時間: 2025-3-28 12:55 作者: FLAIL 時間: 2025-3-28 15:58 作者: 誘惑 時間: 2025-3-28 21:17 作者: 報復 時間: 2025-3-28 23:01 作者: 實現(xiàn) 時間: 2025-3-29 06:38
Identification of Active Oxygen Species over Fe Complexes in Zeolites,analyzed. Particular attention is paid to a recently discovered oxygen species O. formed upon N.O decomposition over Fe complexes in zeolites. High reactivity of α-oxygen coupled with the high concentration allow to reliably identify its participation in the oxidation of methane to methanol and benz作者: travail 時間: 2025-3-29 08:49
Catalysis Using Guest Single and Mixed Oxides in Host Zeolite Matrices,ibility to (i) stabilize (mixed) oxide nanoparticles with unusual catalytic properties, (ii) combine sorption characteristics of the microporous material with the reactivity characteristics of the oxide, (iii) have synergetic interactions between isolated and multinuclear metal-oxide species and (iv作者: 聲明 時間: 2025-3-29 14:23
Reactivity Theory of Zinc Cation Species in Zeolites,ng ab initio methods. We studied the relation between stability of a site and its catalytic activity. In addition to cationic positions formed by a zeolitic ring with two Al ions, the sites with distantly placed aluminiums were also studied. It was shown that the latter tend to form oxygen bridged z作者: Hormones 時間: 2025-3-29 16:49 作者: 痛苦一生 時間: 2025-3-29 20:47
, Simulation of Cu-Species in Zeolites: Siting, Coordination, UV-Vis Spectra and Reactivity, systems is discussed. The latter are able to discriminate between different types of sites in a given framework and between different frameworks. Two types of Cu. sites are identified. Type I sites are found at the channel walls with Cu. coordinated to 3 – 4 oxygen atoms of a five- or six-membered 作者: 喚醒 時間: 2025-3-30 03:43
Asymmetric Oxidation of Sulphide on Metal Ion Planted in Mesoporous MCM-41,llapse of the mesoporous structure of MCM-41 was observed after the TIE treatment. The cations of Al, Ti, Cr, Mn, Zn, or Zr could be incorporated in MCM-41 with high dispersion, while Fe, Co, Ni, Cu, Ga, Pd, or Pt formed nano-scale particles on the outside of the MCM-41 particles. The reaction mecha作者: 猛烈責罵 時間: 2025-3-30 04:51
Photocatalysis of Cations Incorporated within Zeolites, performance for the decomposition of NOx (NO, N.O) into N. and O. at 275 K. In-situ ESR, UV-VIS, photoluminescence and XAFS (XANES and FT-EXAFS) investigations revealed that the transition metal ions exist in a highly dispersed state with a linear 2-coordination sphere within the pores of the ZSM-5作者: 他日關(guān)稅重重 時間: 2025-3-30 09:55 作者: 亞當心理陰影 時間: 2025-3-30 12:25 作者: Exposition 時間: 2025-3-30 17:41
Catalysis by Novel Carbon-Based Materials,s hydrocarbons by means of the so-called catalytic matrix synthesis to synthesise a wide range of carbon materials and carbon-carbonaceous composite materials (CCM) of globular, filamentous and globular-filamentous textures with a narrow distribution of physicochemical properties of the carbon phase作者: 搜集 時間: 2025-3-30 20:54 作者: 駕駛 時間: 2025-3-31 04:07 作者: 去才蔑視 時間: 2025-3-31 08:10
Catalysis by Novel Carbon-Based Materials,formation and stabilization of catalyst active component particles and, finally, its catalytic behaviour. Some specific adsorptive features of filamentous and globular-filamentous CCM caused by a remarkable amount of slit-like pores built in their textures were revealed.作者: Interregnum 時間: 2025-3-31 10:17 作者: folliculitis 時間: 2025-3-31 15:11 作者: CHART 時間: 2025-3-31 19:19
Anatomy and Physiology of the Voiceformation and stabilization of catalyst active component particles and, finally, its catalytic behaviour. Some specific adsorptive features of filamentous and globular-filamentous CCM caused by a remarkable amount of slit-like pores built in their textures were revealed.作者: Modify 時間: 2025-4-1 01:32
Catalysis by Unique Metal Ion Structures in Solid MatricesFrom Science to Appl作者: 平息 時間: 2025-4-1 05:06 作者: 典型 時間: 2025-4-1 08:26
Tatiana V. Gruzdeva,Oleg V. Khamisov choice are twice: i) in the zeolitic family with MFI structure two members, Fe-silicalite and Ti-silicalite, show very interesting catalytic properties in partial oxidation reactions; ii) the properties of the purely siliceous structure (silicalite) where the heteroatoms are guested has been thoroughly investigated.作者: Precursor 時間: 2025-4-1 12:21
Migration of Ti and Fe from Framework to Extraframework Positions in Zeolitic Materials: Spectrosco choice are twice: i) in the zeolitic family with MFI structure two members, Fe-silicalite and Ti-silicalite, show very interesting catalytic properties in partial oxidation reactions; ii) the properties of the purely siliceous structure (silicalite) where the heteroatoms are guested has been thoroughly investigated.
