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標(biāo)題: Titlebook: Buffers for pH and Metal Ion Control; D. D. Perrin,Boyd Dempsey Book 1974 D. D. Perrin and Boyd Dempsey 1974 Ampholyte.Chromat.Titration.a [打印本頁]

作者: 信賴    時間: 2025-3-21 19:56
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作者: maladorit    時間: 2025-3-21 22:34

作者: DAMP    時間: 2025-3-22 02:01

作者: ALOFT    時間: 2025-3-22 04:41

作者: Systemic    時間: 2025-3-22 10:06

作者: Root494    時間: 2025-3-22 16:58
Purification of Substances used in Buffers,torage, when there is evidence of decomposition, or when known impurity levels in reagents are unacceptable, further purification is required. Where possible, the strengths of solutions prepared from substances of doubtful purity or degree of hydration should be confirmed by titration.
作者: 盤旋    時間: 2025-3-22 19:51

作者: 鞭打    時間: 2025-3-23 00:35

作者: 易發(fā)怒    時間: 2025-3-23 02:16

作者: 驚呼    時間: 2025-3-23 08:02

作者: 反叛者    時間: 2025-3-23 13:27
M.C. Escher e il piano iperbolicochange in pH. This resistance to change in the free hydrogen ion concentration of a solution was described by Fernbach and Hubert (1900) as ‘buffering’. In studies of the enzyme, amylase, they found that a partly neutralized solution of phosphoric acid acted as a ‘protection against abrupt changes i
作者: Confirm    時間: 2025-3-23 17:05

作者: 方舟    時間: 2025-3-23 21:47

作者: Benzodiazepines    時間: 2025-3-24 00:46

作者: 大看臺    時間: 2025-3-24 02:46
Quando il cielo ci cade sulla testaith the nature of the solvent. The lower alcohols resemble water, in that they can form the ions ROH. and RO. , but their dissociation is less than for water ((p.=16.7, P.=19.1, cf. p.= 14.0). Consequently, substances dissolved in alcohols are weaker acids and bases than in water. Other factors infl
作者: GROWL    時間: 2025-3-24 09:13
Quando il cielo ci cade sulla testa0.M are difficult to maintain in the presence of adventitious complexing agents, hydrolytic equilibria, adsorption and, possibly, contamination. Many problems can be overcome by the use of metal-ion buffers which provide a controlled source of free metal ions in a manner similar to the regulation of
作者: transplantation    時間: 2025-3-24 12:19
: un’occasione per parlare di numeri primiistilled or de-ionized water. The drying procedure is important because many substances are hygroscopic. When substances are known to deteriorate on storage, when there is evidence of decomposition, or when known impurity levels in reagents are unacceptable, further purification is required. Where p
作者: harrow    時間: 2025-3-24 16:26
: un film e un invito alla topologia dried to constant composition. The distilled water used as solvent should have been recently boiled to remove dissolved carbon dioxide and have been protected from contamination by atmospheric carbon dioxide while cooling. (This precaution is unnecessary in preparing buffer solutions having pH valu
作者: recession    時間: 2025-3-24 20:43

作者: 彎曲的人    時間: 2025-3-25 00:03

作者: 等待    時間: 2025-3-25 06:31

作者: Project    時間: 2025-3-25 08:45
The Theory of Buffer Action,An acid is a species such as the ammonium ion or the acetic acid molecule which has a tendency to lose a proton. A base (such as the ammonia molecule or the acetate anion) is able to accept a proton. Hence for every acid, HA, there is a conjugate base, A., and for every base, B, there is a conjugate acid, BH..
作者: Bouquet    時間: 2025-3-25 13:22
Appendices,Tables 10.1 and 10.2 enable buffer tables to be constructed for use at a constant ionic strength of 0.1 for monoacidic bases or monobasic acids, given the appropriate ‘practical’ p.’. Where necessary, this can be calculated from the thermodynamic value in Appendix III by using Table 2.3.
作者: Seizure    時間: 2025-3-25 17:26
Applications of pH Buffers, is clearly the most important single factor in choosing a buffer for any particular application and reference to lists of p. values such as those given in Appendix III provides a rapid indication of possible buffer substances.
作者: Glutinous    時間: 2025-3-25 23:15
Practical Limitations in the use of Buffers,se. For a buffer to be effective, its pH must be within the range p. ± 1, or preferably, within p. ± 0.5. The former scarcity of buffer substances with a pH range 6 to 8 frequently led to the use of buffers such as phosphate or Tris in pH regions where they had little buffer capacity.
作者: hegemony    時間: 2025-3-26 01:05

作者: 敵手    時間: 2025-3-26 05:41
Metal-Ion Buffers,0.M are difficult to maintain in the presence of adventitious complexing agents, hydrolytic equilibria, adsorption and, possibly, contamination. Many problems can be overcome by the use of metal-ion buffers which provide a controlled source of free metal ions in a manner similar to the regulation of hydrogen ion concentration by pH buffers.
作者: Precursor    時間: 2025-3-26 12:32
https://doi.org/10.1007/978-94-009-5874-6Ampholyte; Chromat; Titration; amines; biochemistry; chemical reaction; chromatography; electrolyte; electro
作者: Ejaculate    時間: 2025-3-26 14:50

作者: 連系    時間: 2025-3-26 20:14

作者: Colonnade    時間: 2025-3-26 22:36
Amleto e il teatro nell’era scientificase. For a buffer to be effective, its pH must be within the range p. ± 1, or preferably, within p. ± 0.5. The former scarcity of buffer substances with a pH range 6 to 8 frequently led to the use of buffers such as phosphate or Tris in pH regions where they had little buffer capacity.
作者: 向下    時間: 2025-3-27 05:00

作者: investigate    時間: 2025-3-27 07:29

作者: Canyon    時間: 2025-3-27 13:17
Introduction,change in pH. This resistance to change in the free hydrogen ion concentration of a solution was described by Fernbach and Hubert (1900) as ‘buffering’. In studies of the enzyme, amylase, they found that a partly neutralized solution of phosphoric acid acted as a ‘protection against abrupt changes i
作者: 清真寺    時間: 2025-3-27 13:37
Applications of pH Buffers, is clearly the most important single factor in choosing a buffer for any particular application and reference to lists of p. values such as those given in Appendix III provides a rapid indication of possible buffer substances.
作者: 刺耳    時間: 2025-3-27 18:23
Practical Limitations in the use of Buffers,se. For a buffer to be effective, its pH must be within the range p. ± 1, or preferably, within p. ± 0.5. The former scarcity of buffer substances with a pH range 6 to 8 frequently led to the use of buffers such as phosphate or Tris in pH regions where they had little buffer capacity.
作者: 大看臺    時間: 2025-3-27 22:11

作者: ARBOR    時間: 2025-3-28 02:38

作者: 直覺沒有    時間: 2025-3-28 09:32
Metal-Ion Buffers,0.M are difficult to maintain in the presence of adventitious complexing agents, hydrolytic equilibria, adsorption and, possibly, contamination. Many problems can be overcome by the use of metal-ion buffers which provide a controlled source of free metal ions in a manner similar to the regulation of
作者: projectile    時間: 2025-3-28 11:43

作者: 比喻好    時間: 2025-3-28 16:52
Preparation of Buffer Solutions, dried to constant composition. The distilled water used as solvent should have been recently boiled to remove dissolved carbon dioxide and have been protected from contamination by atmospheric carbon dioxide while cooling. (This precaution is unnecessary in preparing buffer solutions having pH valu
作者: lethal    時間: 2025-3-28 22:25

作者: 無彈性    時間: 2025-3-29 01:03
and mixed solvent systems. In recent years there has been a significant expansion in the range of available buffers, particularly for biological studies, largely in conse- quence of the development of many zwiUerionic buffers by Good et al. (1966). These are described in Chapter 3.978-0-412-21890-3978-94-009-5874-6




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